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Stereoselectivity in enthalpy changes accompanying the formation of metal complexes of histidine and other amino-acids

✍ Scribed by D.S. Barnes; L.D. Pettit


Book ID
118908750
Publisher
Elsevier Science
Year
1971
Weight
381 KB
Volume
33
Category
Article
ISSN
0022-1902

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## Abstract Enantioselective synthesis of phenylalanine was performed by reacting phenylpyruvic acid with pyridoxamine followed by ketimine‐aldimine isomerization of the __Schiff__ base formed catalyzed by an optically active copper (II)‐complex. By UV and CD measurements it was shown that the enan