Stereoselectivity in Diels—Alder Reactions of Diene-Substituted N-Alkoxycarbonyl-1,2-dihydropyridines.
✍ Scribed by Grant R. Krow; Qiuli Huang; Steven W. Szczepanski; Fredrick H. Hausheer; Patrick J. Carroll
- Publisher
- John Wiley and Sons
- Year
- 2007
- Weight
- 40 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0931-7597
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The N-substituted isomeric (4Z,5Z)-and (4E,5Z)-4,5-diethylideneoxazolidin-2-ones 5 and 6 were synthesized, the latter being favored during the one-step process from the a-diketone 1c and different isocyanates. The steric interaction between the N-substituent and the Me group attached to the exocycli
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