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Stereoselective total synthesis of (.+-.)-perhydrogephyrotoxin. Synthetic applications of directed 2-azonia-[3,3]-sigmatropic rearrangements

โœ Scribed by Overman, Larry E.; Fukaya, Chikara


Book ID
126989769
Publisher
American Chemical Society
Year
1980
Tongue
English
Weight
411 KB
Volume
102
Category
Article
ISSN
0002-7863

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Hydroxyl-directed stereoselective [2,3]
โœ Tsuneo Sato; Junzo Otera ๐Ÿ“‚ Article ๐Ÿ“… 1994 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 226 KB

## The [Z3l sigmatropic rearrangement of )chydrovalkyl rmethoxyallyl sulfoxids occurs in a highly swreoselecdve manner to give &hydroxy-(E)-enals; a novel mechanism involving interaction between the hydroxy oxygen and rhe sulflnyl sa&w is proposed.