S)-2-Phenylpropionic acid was stereoselectively obtained by the AgBF 4catalyzed phenyl-rearrangement of (S)-2-chloropropiophenone dimethyl acetal, while the photoirradiafion of (S)-or (R)-2-chloropropiophenone afforded partially racemized (S)or (R)-2-phenylpropionic acid, respectively. An intramolec
โฆ LIBER โฆ
Stereoselective thermal rearrangements of 2-phenyl-alkenylidenecyclopropanes
โ Scribed by Timothy B. Patrick; Edward C. Haynie; William J. Probst
- Publisher
- Elsevier Science
- Year
- 1971
- Tongue
- French
- Weight
- 96 KB
- Volume
- 12
- Category
- Article
- ISSN
- 0040-4039
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2-Isoxazolines may be regarded as cyclic ethers of S-ketol oximes, although ring I is remarkably stable towards hydrolytic agents. Since it is known that oxime ethers may undergo the Beckmaan rearrangement, it was considered probable that under suitable conditions 2-isoxazolines should also give thi