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Stereoselective Synthesis of β-1-O-Acyl Derivatives of Carbohydrates: An Application of the Cesium Effect.

✍ Scribed by Horst Kunz; Richard Kullmann; Peter Wernig; Jörg Zimmer


Book ID
103405018
Publisher
Elsevier Science
Year
1992
Tongue
French
Weight
258 KB
Volume
33
Category
Article
ISSN
0040-4039

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## Abstract ‘__O__‐Acyl isopeptide method’ is an efficient synthetic method for peptides. We designed ‘__O__‐acyl isodipeptide units’, Boc‐Ser/Thr(Fmoc‐Xaa)‐OH, as important building blocks to enable routine use of the __O__‐acyl isopeptide method. In the synthesis of an Aβ1–42 isopeptide using __O