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Stereoselective Synthesis of Woody Fragrances Related to Georgyone and Arborone

โœ Scribed by Hicken, Erik J.; Corey, E. J.


Book ID
120717503
Publisher
American Chemical Society
Year
2008
Tongue
English
Weight
86 KB
Volume
10
Category
Article
ISSN
1523-7060

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In relation to the total synthesis of the furaquinocins, stereoselective methylenation of chiral aldehyde 5 is described. The diastereoselectivity of epoxides 6s/6b is high when stabilized sulfur ylides are employed. A double stereo-differentiation phenomenon was observed for the aminosulfoxonium yl