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Stereoselective synthesis of vinylogous peptides

✍ Scribed by Claude Grison; Stéphane Genève; Etienne Halbin; Philippe Coutrot

Book ID
108371224
Publisher
Elsevier Science
Year
2001
Tongue
French
Weight
400 KB
Volume
57
Category
Article
ISSN
0040-4020

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ChemInform Abstract: Stereoselective Syn
ChemInform Abstract: Stereoselective Synthesis of Vinylogous Peptides.
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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v

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Chiral vinylogous amino sulfonic acids (vs-amino acids) were synthesized starting from either L-or D-α-amino acids via N-BocϪα-amino aldehydes. Wittig-Horner reaction with methyl (or ethyl) diethylphosphoryl methanesulfonate and nBuLi gave the corresponding α,β-unsaturated sulfonates in high yield a