Stereoselective Synthesis of Trifluoromethylated Vicinal Ethylenediamines with α-Amino N-tert-Butanesulfinimines and TMSCF3.
✍ Scribed by G. K. Surya Prakash; Mihirbaran Mandal
- Book ID
- 101939195
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 40 KB
- Volume
- 33
- Category
- Article
- ISSN
- 0931-7597
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3S, 4R)-and (3R, 4S)-3-hydroxy-4-rerr-butyl &lactams on exposure to IM NaOCl and a catalytic amount of 2,2,6,6-tetramethy lpiperidinyl-l-oxyl (TEMPO) afforded et-amino acid N-carboxy anhydrides formally derived from both (S)-and (R)-tert-leucine amino acids. 01997 Published byElsevierScienceLtd.