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Stereoselective synthesis of the tricyclic core ABC-rings of nakadomarin and manzamine from a common intermediate

✍ Scribed by Philip Magnus; Mark R Fielding; Charles Wells; Vince Lynch

Publisher: Elsevier Science
Year: 2002
Tongue: French
Weight: 263 KB
Volume: 43
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)02301-2

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✦ Synopsis

Pauson-Khand cyclization of the enamide 9 proceeds in trifluoroethanol to give cyclopentenone 10, which on hydrogenation gives 11, having the core ABC-rings of nakadomarin 1.

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