Stereoselective synthesis of polyenic alcohols. A new route to the leukotrienes B.
β Scribed by D Guillerm; C Linstrumelle
- Publisher
- Elsevier Science
- Year
- 1986
- Tongue
- French
- Weight
- 207 KB
- Volume
- 27
- Category
- Article
- ISSN
- 0040-4039
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l!he use of isoprene for conf&ruction of terpenoids is one of the moat challensing problem6 of 4&hetlo chemlstq. Thermal? and oatalyt~ic~~~ ieopreno oligo-and telomerisation into terpenolds or related oompormdr, is well documented in literature (most4 in patent form). This way, aa a rule, allows one
## Abstract For Abstract see ChemInform Abstract in Full Text.
20.1 Hz, 1 F, CH 2 F). Οͺ Selected NOEs (CDCl 3 ): {3-H} enhanced (Q, 2 Me), 47.83 (D, C-3), 57.07 (Dd, 3 J C,F Ο 5.5 Hz, C-4), 62.10 (T, 2 OCH 2 ), 70.90 (D, C-2), 71.76 (Dd, 2 J C,F Ο 19.0 Hz, C-5), 4-H (2%), 5-H (1%), 2-CH 2 (2%), 1Π-OCH 2 (0.5%) and 1Π-CH 2 (1%); {4-H} enhanced 3-H (2%), 5-H (2.5