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Stereoselective Synthesis of Optically Active α-Hydroxy Ketones and a nti -1,2-Diols via Asymmetric Transfer Hydrogenation of Unsymmetrically Substituted 1,2-Diketones

✍ Scribed by Koike, Takashi; Murata, Kunihiko; Ikariya, Takao


Book ID
121864771
Publisher
American Chemical Society
Year
2000
Tongue
English
Weight
60 KB
Volume
2
Category
Article
ISSN
1523-7060

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## Abstract The reactivity of verbenone epoxide (**5**), a terpenoid from the pinane series, towards different aliphatic and aromatic aldehydes in the presence of natural montmorillonite (askanite–bentonite) clay has been studied. A series of mechanistically different transformations afforded a num