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Stereoselective synthesis of (−)-N-Boc-statine and (−)-N-Boc-Norstatine

✍ Scribed by G. Veeresha; Apurba Datta


Book ID
104257464
Publisher
Elsevier Science
Year
1997
Tongue
French
Weight
128 KB
Volume
38
Category
Article
ISSN
0040-4039

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✦ Synopsis


An efficient synthesis of optically pure N-Boc-statine ( 9) and N-Boc-norstatine (11) has been developed v/a a syn selective Grignard reaction of N-Boc-leucinal with allyl-or vinylmagnesium bromide.


📜 SIMILAR VOLUMES


Stereoselective alkylation of N-Boc-2-py
✍ Adriano O. Maldaner; Ronaldo A. Pilli 📂 Article 📅 1999 🏛 Elsevier Science 🌐 French ⚖ 615 KB

Alkylation of ¢nolates of mcvvsubstituted N-BOc Iactams 4-6 afforded trans-disubstituted lactams as the major is~ner. In the pyrrolidinon¢ sa'ies, 1,3-induction seems to be ruled by stetic interacti~s and the diasterc~electi~m is low fc¢ the alkylation of enolates with small substitumts at C-5 (e.&,

ChemInform Abstract: Stereoselective Alk
✍ Adriano O. Maldaner; Ronaldo A. Pilli 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 30 KB 👁 2 views

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v