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Stereoselective Synthesis of meso -α,α‘-Bis(Chloromercurio)-α,α‘-bis(trimethylsilyl)- m -xylene

✍ Scribed by Tschinkl, Martin; Schier, Annette; Riede, Jürgen; Mehltretter, Gerald; Gabbaï, François P.

Book ID
125929202
Publisher
American Chemical Society
Year
1998
Tongue
English
Weight
58 KB
Volume
17
Category
Article
ISSN
0276-7333

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📜 SIMILAR VOLUMES

ChemInform Abstract: Stereoselective Syn
ChemInform Abstract: Stereoselective Synthesis of meso-α,α′-Bis(chloromercurio)-α,α′-bis (trimethylsilyl)-m-xylene.
✍ M. TSCHINKL; A. SCHIER; J. RIEDE; G. MEHLTRETTER; F. P. GABBAI 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 30 KB 👁 1 views

Stereoselective Synthesis of meso-α,α'-Bis(chloromercurio)-α,α'-bis (trimethylsilyl)-m-xylene. -Exclusive meso selectivity is observed in the formation of the title compound whose structure is confirmed by an X-ray single-crystal analysis. -(TSCHINKL, M.; SCHIER, A.; RIEDE,

Anodic oxidation of α,α′-bis(trimethylsi
Anodic oxidation of α,α′-bis(trimethylsilyl)xylenes in alcohols
✍ Toshio Koizumi; Toshio Fuchigami; Tsutomu Nonaka 📂 Article 📅 1988 🏛 Elsevier Science 🌐 English ⚖ 583 KB

Anodic oxidation of a,cz'-bis(trimethylsilyl)-o-, -m-, and -p-xylenes (l-3) was comparativety examined. a-Trimethyliilylation of xylenes markedly decreased their oxidation potentials while additional a'trimethylsilylation resulted in no further change. The silylxylenes I-3 underwent anodic alkoxylat