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Stereoselective synthesis of linear and angular triquinanes skeletons via the zinca-ene-allene reactions

✍ Scribed by Christophe Meyer; Ilane Marek; Jean-F. Normant

Publisher
Elsevier Science
Year
1996
Tongue
French
Weight
189 KB
Volume
37
Category
Article
ISSN
0040-4039

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## Abstract The racemic spirosesquiterpenes β‐acorenol (**1**), β‐acoradiene (**2**), acorenone‐B (**3**) and acorenone (**4**) (__Scheme 2__) have been synthesized in a simple, flexible and highly stereoselective manner from the ester **5**. The key step (__Schemes 3__ and __4__), an intramolecula