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Stereoselective synthesis of homoallylic alcohols containingtrisubstituted olefinic double bonds

✍ Scribed by Paul R. McGuirk; Anthony Marfat; Paul Helquist

Book ID
104245826
Publisher
Elsevier Science
Year
1978
Tongue
French
Weight
262 KB
Volume
19
Category
Article
ISSN
0040-4039

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πŸ“œ SIMILAR VOLUMES

Stereoselective synthesis of alcohols, X
Stereoselective synthesis of alcohols, XXXVI. Stereoselective generation of homoallyl alcohols having quaternary stereogenic centers
✍ Hoffmann, Reinhard W. ;Schlapbach, Achim πŸ“‚ Article πŸ“… 1990 πŸ› John Wiley and Sons 🌐 English βš– 617 KB

## Abstract __E__‐ and __Z__‐γ,γ‐disubstituted allylboronates 12 have been generated by the carbocupration of alkynes and subsequent homologation. These allylboronates add to aldehydes, forming the homoallyl alcohols 13 and 14 with 88–99% simple diastereoselectivity. The highest diastereoselectivit