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Stereoselective synthesis of heterocycles by desulfurisation of condensed thiazolidin-2-ones

โœ Scribed by J.A.M. Hamersma; W.N. Speckamp


Book ID
108374433
Publisher
Elsevier Science
Year
1985
Tongue
French
Weight
893 KB
Volume
41
Category
Article
ISSN
0040-4020

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Cationic heterocyclization One step synt
โœ J.B.P.A. Wijnberg; W.N. Speckamp; J.J.J. de Boer ๐Ÿ“‚ Article ๐Ÿ“… 1974 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 160 KB

Dimerizations of cyclic enamines 1 (R=H2) occurring via iminium intermediates 2 (R=H2) are well-known 1) and have been applied recently in alkaloid synthe-sis2). Schematically the overall process can be represented as follows: R'