𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Stereoselective synthesis of (E)-β-fluoro-α,β-unsaturated esters by carbonylation of (E)-2-fluoro-1-iodo-1-alkenyliodonium salts

✍ Scribed by Shoji Hara; Kenichi Yamamoto; Masanori Yoshida; Tsuyoshi Fukuhara; Norihiko Yoneda


Publisher
Elsevier Science
Year
1999
Tongue
French
Weight
184 KB
Volume
40
Category
Article
ISSN
0040-4039

No coin nor oath required. For personal study only.

✦ Synopsis


Fluoro-a,~-umanamed esters were stereoselectively ol~ined by the palladium-catalyzed carbonylation reaction of (E)-2-fluoro-l-iodo-l-alkenyliodmium salts obtained by the addition of iedo~uene difluoride to l-alk'ym~


📜 SIMILAR VOLUMES


Synthesis of 1-(2-deoxy-2-fluoro-β-D-ara
✍ J. E. Swigor; K. A. Pittman 📂 Article 📅 1985 🏛 John Wiley and Sons 🌐 French ⚖ 232 KB 👁 1 views

The synthesis of t h e title canpound (7) is described. [2-14C] cytosine (I) is treated with an aqueous mixture of sodium bisulfite and sodium sulfate at 8OoC for 30 rnin. The resulting solid is then treated with aqueous sodiun hydroxide and passed through a cation exchange colunn, producing [ Z-14C