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Stereoselective synthesis of dl-18,19-dihydroantirhine and dl-3-epi-18,19-dihydroantirhine

โœ Scribed by Mauri Lounasmaa; Reija Jokela


Publisher
Elsevier Science
Year
1989
Tongue
French
Weight
440 KB
Volume
45
Category
Article
ISSN
0040-4020

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Quassiols A were synthesized enantioselectively by using baker's yeast reduction and asymmetric dihydroxylation, but their optical properties were not identical to that of natural quassiol A. Stereostructure of natural quassiol A was proposed.