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Stereoselective synthesis of (±)-clavukerin A and (±)-isoclavukerin A based on palladium-catalyzed reductive cleavage of alkenylcyclopropanes with formic acid

✍ Scribed by Isao Shimizu; Tomoko Ishikawa

Book ID
104214416
Publisher
Elsevier Science
Year
1994
Tongue
French
Weight
243 KB
Volume
35
Category
Article
ISSN
0040-4039

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✦ Synopsis

Abshurcl: (f)-Clavukerin A and (&)-isuclavukeriu A were syuU~esizc!d srereoseleclivcly utilizing stereospecific palladiumcalalyzed reductive cleavage of alkenylcyclopropuues with Curmic acid.

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Effect of Solvent and Acid-Base on Palla
Effect of Solvent and Acid-Base on Palladium (II)-catalyzed Dicarbonylation of Terminal Acetylenes: a General, Efficient and Stereoselective Synthesis of Maleic Diesters and Maleic Anhydrides
✍ Jin-Hang Li; Huan-Feng Jiang; Ming-Cai Chen 📂 Article 📅 2010 🏛 John Wiley and Sons 🌐 English ⚖ 356 KB 👁 1 views

## Abstract The productions of maleic diesters and maleic anhydrides depend on the effect of solvent and acid‐base in palladium‐catalyzed dicarbonylation of terminal acetylenes. For primary and secondary alcohol in benzene, only maleic diesters were obtained stereospecifically from the dicarbonylat