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✦ LIBER ✦
Stereoselective Synthesis of cis - and trans -2,3-Disubstituted Tetrahydrofurans via Oxonium−Prins Cyclization: Access to the Cordigol Ring System
✍ Scribed by Spivey, Alan C.; Laraia, Luca; Bayly, Andrew R.; Rzepa, Henry S.; White, Andrew J. P.
- Book ID
- 126962620
- Publisher
- American Chemical Society
- Year
- 2010
- Tongue
- English
- Weight
- 418 KB
- Volume
- 12
- Category
- Article
- ISSN
- 1523-7060
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ChemInform Abstract: Stereoselective Syn
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Diastereoselective construction of cis 2
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Diastereoselective construction of 2,6-disubstituted tetrahydropyrans with an exocyclic double bond was achieved via the In(OTf) 3 -catalyzed intramolecular 2,5-oxonium-ene cyclization. Its application was further demonstrated by the synthesis of a common intermediate for both zampanolide and dactyl
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