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Stereoselective synthesis of cis-4,7-disubstituted 4,7-dihydroxy-4,7-dihydro[2.2]paracyclophanes

✍ Scribed by N. V. Vorontsova; V. I. Rozenberg; E. V. Vorontsov; D. Yu. Antonov; Z. A. Starikova; Yu. N. Bubnov

Book ID
110401752
Publisher
Springer
Year
2002
Tongue
English
Weight
457 KB
Volume
51
Category
Article
ISSN
1573-9171

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πŸ“œ SIMILAR VOLUMES

Unusual Rearrangements of cis-4,7-Disubs
Unusual Rearrangements of cis-4,7-Disubstituted 4,7-Dihydro4,7-dihydroxy[2.2]paracyclophanes on Dehydration: Stereoselective Formation of Planar Chiral Cyclohexadienones
✍ Natalia Vorontsova; Valeria Rozenberg; Evgenii Vorontsov; Dmitrii Antonov; Zoya πŸ“‚ Article πŸ“… 2003 πŸ› John Wiley and Sons 🌐 English βš– 665 KB

## Abstract Under acid conditions, __cis__‐4,7‐disubstituted 4,7‐dihydro‐4,7‐dihydroxy[2.2]paracyclophanes undergo dehydration accompanied by rearrangement, affording cyclohexadienone derivatives as major products and with polysubstituted phenols being formed as minor products. The formation of eit