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Stereoselective synthesis of chiral precursors to cyclobutane carbocyclic nucleosides and oligopeptides

✍ Scribed by Pablo D. Rouge; Albertina G. Moglioni; Graciela Y. Moltrasio; Rosa M. Ortuño

Publisher
Elsevier Science
Year
2003
Tongue
English
Weight
151 KB
Volume
14
Category
Article
ISSN
0957-4166

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✦ Synopsis

Versatile and highly efficient synthetic routes leading to optically active cyclobutanones, g-amino acids and d-amino alcohols are described. These compounds are relevant synthetic precursors to enantiopure cyclobutane carbocyclic nucleosides and oligopeptides. (-)-(S)-Verbenone is the chiral starting material used and the key synthetic steps involve concerted rearrangements in acidic medium.

📜 SIMILAR VOLUMES

ChemInform Abstract: Chiral Synthesis of
ChemInform Abstract: Chiral Synthesis of Carbocyclic Nucleoside Analogues from Non-Carbohydrate Precursors
✍ Fabio Casu; Maria Assunta Chiacchio; Roberto Romeo; Giuseppe Gumina 📂 Article 📅 2008 🏛 John Wiley and Sons ⚖ 15 KB 👁 2 views

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