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Stereoselective Synthesis of C- and N-Ketosides by Lewis Acid Catalyzed C- and N-Glycosidation of Alkynyl, Phenyl, and Methyl Ketoses.

✍ Scribed by Ana M. Gomez; Clara Uriel; Slawomir Jarosz; Serafin Valverde; J. Cristobal Lopez

Publisher
John Wiley and Sons
Year
2004
Weight
158 KB
Volume
35
Category
Article
ISSN
0931-7597

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Stereoselective Synthesis of C- and N-Ke
Stereoselective Synthesis of C- and N-Ketosides by Lewis Acid-Catalyzed C- and N-Glycosidation of Alkynyl, Phenyl, and Methyl Ketoses
✍ AnaΒ M. GΓ³mez; Clara Uriel; Slawomir Jarosz; SerafΓ­n Valverde; J.Β CristΓ³bal LΓ³pez πŸ“‚ Article πŸ“… 2003 πŸ› John Wiley and Sons 🌐 English βš– 196 KB

## Abstract C‐Ketosides can be prepared conveniently, in a stereoselective manner, from alkynyl, phenyl and methyl glucopyranose hemiketals by reaction with carbon nucleophiles in the presence of Lewis acids. The reaction of the hemiketals with trimethylsilyl azide provides an efficient route to th