Stereoselective Synthesis of Alcohols, XXXVII. Origins of Stereoselectivity in Reactions of α-Substituted Allylboronates with Aldehydes
✍ Scribed by Hoffmann, Reinhard W. ;Jens Wolff, J.
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 1991
- Tongue
- English
- Weight
- 686 KB
- Volume
- 124
- Category
- Article
- ISSN
- 0009-2940
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Allylboration reaction / Asymmetric induction / Calculations, force-field / Transition-state models The direction (Cramlanti-Cram) and the extent of asymmetric induction on addition of crotylboronates to a range of chiral aldehydes was investigated. A reversal in the sense of the asymmetric inducti
Reagent control of stereoselectivity / Z-Enol ether, formation of / Allylboronates, addition to aldehydes a C p h a O X p (4) & U-i.l&lOXy~O@bO~n8t& @) l b m the ccchtorocrotylboronates 1. Addith of the phenoxy compound to aldohydes gave the homoallyl alcohols !5/6 as Z/E mixtweq addition of the met
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