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Stereoselective Synthesis of a Series of New N-Alkyl-3-hydroxypiperidine Derivatives Containing a Hemiketal

✍ Scribed by Haibo Wang; Hairong Luo; Xiaofeng Ma; Wei Zou; Huawu Shao

Book ID: 102831431
Publisher: John Wiley and Sons
Year: 2011
Tongue: English
Weight: 587 KB
Volume: 2011
Category: Article
ISSN: 1434-193X
DOI: 10.1002/ejoc.201100533

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## Abstract magnified image From the known lactone (__S__)‐**4**, easily derived from L‐glutamic acid, a scalable approach to chiral building block __O__‐silylated 3‐hydroxypiperidin‐2‐one **3** and alkaloid **1** was achieved in five and six‐steps respectively. The key steps are a chemoselective