Stereoselective Synthesis of (2 Z ,4 E )-2,4-Pentadien-1-ols via Sequential 1,4-Elimination Reaction and [1,2]-Wittig Rearrangement Starting from ( E )-4-Alkoxy-2-butenyl Benzoates
β Scribed by Nakano, Takeo; Soeta, Takahiro; Endo, Kohei; Inomata, Katsuhiko; Ukaji, Yutaka
- Book ID
- 121452576
- Publisher
- American Chemical Society
- Year
- 2013
- Tongue
- English
- Weight
- 526 KB
- Volume
- 78
- Category
- Article
- ISSN
- 0022-3263
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a βFull Textβ option. The original article is trackable v
## Abstract The rearrangement of allylic sulfones induced by the successive treatment with KOtBu and LDA affords the corresponding dienyl alcohols with high selectivity for the formation of the respective (Z)βisomer, due to a synβeffect in the elimination step.