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Stereoselective Synthesis of 1,2-Difunctional Compounds Through the Addition of Organometallic Reagents to Chiral Masked Forms of Glyoxal

โœ Scribed by Gianluca Martelli; Diego Savoia


Publisher
John Wiley and Sons
Year
2003
Weight
52 KB
Volume
34
Category
Article
ISSN
0931-7597

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โœฆ Synopsis


Abstract

For Abstract see ChemInform Abstract in Full Text.


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The chiral formylferrocenes 2-5 have been readily prepared in good yields by ortho-lithiation of the TMS-blocked orunblocked aminoferrocenes and subsequent reaction with DMF. The stereochemistry of the reaction of 2 with organometallic reagents has been examined. Reactions of 2 with Grignard and org

ChemInform Abstract: Diastereoselective