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Stereoselective Synthesis of 1,2-Aminoalcohols by [2,3]-Wittig Rearrangements

✍ Scribed by Meyer, Christophe; Cossy, Janine; Barbazanges, Marion


Book ID
115518298
Publisher
American Chemical Society
Year
2007
Tongue
English
Weight
86 KB
Volume
9
Category
Article
ISSN
1523-7060

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Stereoselective synthesis of 5-O-carbamo
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Stereoselective [2, -Wittig rearrangement of E-and Z-allylic stannyl ethers derived from an isopropylidene L-threitol derivative has been investigated. The E-isomer exhibited best diastereoselectivity and the resulting rearrangement product has been converted to protected polyoxamic acid, an amino