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Stereoselective Synthesis of (1 Z ,3 E )-2-Ethoxycarbonyl-Substituted 1,3-Dienes via Stille Coupling of ( E )-α-Stannyl-α,β-Unsaturated Esters with Alkenyl Halides

✍ Scribed by Zhao, Hong; Dai, Ruchun; Cai, Mingzhong

Book ID
126744682
Publisher
Taylor and Francis Group
Year
2009
Tongue
English
Weight
182 KB
Volume
39
Category
Article
ISSN
0039-7911

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A novel stereoselective synthesis of (Z)
A novel stereoselective synthesis of (Z)-α-arylsulfanyl-α,β-unsaturated ketones via Stille coupling of (E)-α-arylsulfanylvinylstannanes with acyl halides
✍ Fang Yao; Shengyong You; Mingzhong Cai 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 96 KB

## Abstract (__E__)‐α‐Arylsulfanylvinylstannanes react with acyl halides in the presence of a catalytic amount of Pd(PPh~3~)~4~ and CuI cocatalyst to give stereoselectively the corresponding (__Z__)‐α‐arylsulfanyl‐α,β‐unsaturated ketones in good yields. © 2009 Wiley Periodicals, Inc. Heteroatom Che