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Stereoselective Synthesis of 1-Aminocyclopropanecarboxylic Acid Derivatives via Ylide Cyclopropanation of Dehydroamino Acid Derivatives

✍ Scribed by Rui Zhou; Xianming Deng; Juncheng Zheng; Qi Sheng; Xiuli Sun; Yong Tang


Publisher
John Wiley and Sons
Year
2011
Tongue
English
Weight
133 KB
Volume
29
Category
Article
ISSN
0256-7660

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## Abstract This account concentrates on our new methodologies for the synthesis of fluorine analogues of amino acids and their derivatives using the Reformatsky‐type reactions of ethyl bromodifluoroacetate and ethyl dibromofluoroacetate with imines promoted by the Wilkinson catalyst. First, we pre