Stereoselective synthesis and stereospecific asymmetric 1,2-rearrangements of chiral sulfinylcyclopropane derivatives
โ Scribed by Kunio Hiroi; Takashi Anzai; Takenobu Ogata; Maki Saito
- Publisher
- Elsevier Science
- Year
- 1990
- Tongue
- French
- Weight
- 256 KB
- Volume
- 31
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
## Abstract For Abstract see ChemInform Abstract in Full Text.
Stereospecific 1,2-rearrangement of cyclopropyl group is described as an efficient route to stereo-defined a-cyclopropyl ketones and cr-cyclopropyl aldols. Acceleration of the reaction by the introduction of trimethylsilyl (TMS) group to the a-position of cyclopropyl group is also noted. ## Cyclop
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