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Stereoselective semi-hydrogenation and deuteration of a diacetylenic precursor of leukotriene B4 methyl ester

✍ Scribed by Renée Pontikis; Yves Le Merrer; Jean-Claude Depezay; Yves Pétillot; Bernard Rousseau; Jean Pierre Beaucourt


Publisher
John Wiley and Sons
Year
1990
Tongue
French
Weight
275 KB
Volume
28
Category
Article
ISSN
0022-2135

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✦ Synopsis


Abstract

[6,7,14,15‐^2^H~4~)‐Leukotriene B~4~ methyl ester was prepared by reduction with deuterium gas of a suitable precursor (deuterium incorporation ≥ 90%). Several catalytic semi‐hydrogenations were effected in order to determine the best conditions for the labeling step.