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Stereoselective Ring-Opening Polymerization of meso -Lactide: Synthesis of Syndiotactic Poly(lactic acid)

✍ Scribed by Ovitt, Tina M.; Coates, Geoffrey W.

Book ID
120572700
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
33 KB
Volume
121
Category
Article
ISSN
0002-7863

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Stereoselective ring-opening polymerizat
Stereoselective ring-opening polymerization of rac-lactide with a single-site, racemic aluminum alkoxide catalyst: Synthesis of stereoblock poly(lactic acid)
✍ Tina M. Ovitt; Geoffrey W. Coates πŸ“‚ Article πŸ“… 2000 πŸ› John Wiley and Sons 🌐 English βš– 160 KB πŸ‘ 1 views

The polymerization of racemic lactide with a racemic aluminum alkoxide catalyst is reported. Microstructural analysis of the polymer produced with 1 H NMR spectroscopy revealed that an isotactic stereoblock poly(lactic acid) formed, where each enantiomerically pure block contained an average of 11 l