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Stereoselective reductive radical cyclization of ketonitriles catalyzed by Cp2TiCl2 in the presence of chlorosilane and zinc

✍ Scribed by Longhu Zhou; Toshikazu Hirao


Book ID
108371300
Publisher
Elsevier Science
Year
2001
Tongue
French
Weight
134 KB
Volume
57
Category
Article
ISSN
0040-4020

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Cp2TiCl2-Catalyzed pinacol-type coupling
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Bis(cyclopentadienyl) titanium dichloride (Cp2TiCI2) exhibits excellent catalytic activity toward the pinacol-type coupling reaction of aliphatic aldehydes with the assistance of zinc powder and chlorosilane.

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