Stereoselective Reactions of (E,E)-2,3,6,7-Tetramethyl-1,8-Bis(trimethylsilyl)octa-2,6-diene with Aldehydes and Acyl Chlorides
✍ Scribed by Chahinez Aouf; Douniazad El Abed; Malika Ibrahim-Ouali; Michel Giorgi; Maurice Santelli
- Publisher
- John Wiley and Sons
- Year
- 2007
- Tongue
- English
- Weight
- 145 KB
- Volume
- 2007
- Category
- Article
- ISSN
- 1434-193X
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A novel C&l-assisted coupling reaction 9f i-chloro-l-aryloyl-3,3-diarylallene (2) and two new thermal cyclization reactiom ti,P 1,1,4,4-tetraaryl-3,6-diaryloylhexa-1,2-diene-5-yne (L) are described.
## Abstract The now corrected X‐ray structure of (2__R__)‐bornane‐10,2‐sultam ((−)‐**1a**), as well as that of its already published __N__‐crotonoyl derivative (−)‐**1d**, were compared with those of the newly synthesized (2__R__)‐fenchane‐8,2‐sultam ((+)‐**5a**), as well as its __N__‐crotonoyl der