Stereoselective Radical Reactions
β Scribed by Gregory Bar; Andrew F. Parsons
- Publisher
- John Wiley and Sons
- Year
- 2003
- Weight
- 49 KB
- Volume
- 34
- Category
- Article
- ISSN
- 0931-7597
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π SIMILAR VOLUMES
Dianions derived from chiral imidazolines la-c, undergo selective one-electron oxidation reactions in the presence of TEMPO (2,2,6, and form metallated radical species. Depending on the reaction conditions the radical intermediate is trapped stereoselectively by TEMPO, or undergoes a dimerization re
The g-acyl thiohydroxamate (l\_) has been found to add tc the chiral acrylate esters ( )and ( ) giving the addrcts ( ) and ( )with modestdecees of?kymmetric induction.
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