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Stereoselective Radical Aryl Migration from Silicon to Carbon †

✍ Scribed by Amrein, Stephan; Bossart, Martin; Vasella, Tomaso; Studer, Armido


Book ID
126956315
Publisher
American Chemical Society
Year
2000
Tongue
English
Weight
222 KB
Volume
65
Category
Article
ISSN
0022-3263

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Stereoselective phenyl migration from si
✍ Armido Studer; Martin Bossart; Hanno Steen 📂 Article 📅 1998 🏛 Elsevier Science 🌐 French ⚖ 253 KB

In the present letter, the first stereoselective radical 1,5 phenyl transfer from silicon to carbon is reported. Diphenyl(trimethylsilyl)silyl ethers, the corresponding germylated and stannylated derivatives, and also some silyl ethers derived from commercially available silicon protecting groups we