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Stereoselective preparation of 2-silylated 1,3-diols and the regioselectivity of their Peterson olefination

✍ Scribed by Jürg Fässler; Anthony Linden; Stefan Bienz

Book ID
108379207
Publisher
Elsevier Science
Year
1999
Tongue
French
Weight
815 KB
Volume
55
Category
Article
ISSN
0040-4020

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ChemInform Abstract: Stereoselective Preparation of 2-Silylated 1,3-Diols and the Regioselectivity of Their Peterson Olefination.
✍ Juerg Faessler; Anthony Linden; Stefan Bienz 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 36 KB 👁 2 views

Stereoselective Preparation of 2-Silylated 1,3-Diols and the Regioselectivity of Their Peterson Olefination. -α-Silylated β-hydroxy ketones can be reduced with high stereoselectivity. The α-silyl group usually dictates the stereochemical outcome and the presence of the β-hydroxy group seems to be i