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Stereoselective Oxidation of Thiacalix[4]arenes with the NaNO3/CF3COOH System.

✍ Scribed by Pavel Lhotak; Jiri Moravek; Tomas Smejkal; Ivan Stibor; Jan Sykora


Book ID
101953382
Publisher
John Wiley and Sons
Year
2003
Weight
52 KB
Volume
34
Category
Article
ISSN
0931-7597

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Stereoselective oxidation of thiacalix[4
✍ Pavel LhotΓ‘k; JiΕ™Δ±́ MorΓ‘vek; TomΓ‘Ε‘ Ε mejkal; Ivan Stibor; Jan SΓ½kora πŸ“‚ Article πŸ“… 2003 πŸ› Elsevier Science 🌐 French βš– 242 KB

A series of alkyl substituted thiacalix [4]arene derivatives (being conformationally mobile or immobilised in the cone conformation) was used as the starting point for this study. It was demonstrated that the NaNO 3 /CF 3 COOH system can serve as an excellent oxidising agent. The oxidation of the br