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Stereoselective nucleophilic addition of butyllithium and triallylborane to [2.2]paracyclophane-4,7-quinone

โœ Scribed by N. V. Vorontsova; V. I. Rozenberg; E. V. Vorontsov; D. Yu. Antonov; Yu. N. Bubnov


Book ID
105595404
Publisher
Springer
Year
2000
Tongue
English
Weight
136 KB
Volume
49
Category
Article
ISSN
1573-9171

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โœ Elena V Sergeeva; Valeria I Rozenberg; Evgenii V Vorontsov; Tat'yana I Danilova; ๐Ÿ“‚ Article ๐Ÿ“… 1996 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 548 KB

Highly diastereoselective nucleophilic addition reactions of organometallic reagents to formyl[2.2]paracyclophane derivatives which were ortho-substituted by hydroxy-, alkoxy-and trimethylsilyloxy-groups are reported. The absolute configuration of the newly formed secondary alcohols is assigned on t