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Stereoselective introduction of hydroxy-groups into the 24-, 25-, and 26-positions of the cholesterol side chain

✍ Scribed by Ishiguro, Masaji; Koizumi, Naoyuki; Yasuda, Mitsuhiro; Ikekawa, Nobuo


Book ID
121440405
Publisher
The Royal Society of Chemistry
Year
1981
Tongue
English
Weight
229 KB
Volume
3
Category
Article
ISSN
0022-4936

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✍ F.J. Sardina; A. MouriΓ±o; L. Castedo πŸ“‚ Article πŸ“… 1983 πŸ› Elsevier Science 🌐 French βš– 214 KB

An efficient, stereospecific synthesis of 25-hydroxy-7,8-dihydroerqosterol, starting from the aldehyde 3 (7 steps, 30,: overally was developed. Key steps are the stereospecific displacement of an allylic carbamate by