✦ LIBER ✦
Stereoselective intramolecular michael addition induced by a thermolabile group: Synthesis of optically active five-membered oxygen-containing rings.
✍ Scribed by Robert Bloch; Matar Seck
- Publisher
- Elsevier Science
- Year
- 1987
- Tongue
- French
- Weight
- 136 KB
- Volume
- 28
- Category
- Article
- ISSN
- 0040-4039
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✦ Synopsis
A tandem Wittig-Michael reaction allows the stereoselective formation of the tricyclic compound 2 from the chiral lactol 1. A retro Diels-Alder reaction high enantsmeric purity.