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Stereoselective interaction of optically active amino acids and esters with (L;valine-N-monoacetato)copper(II)

โœ Scribed by Leach, Bruce E.; Angelici, Robert J.


Book ID
126772667
Publisher
American Chemical Society
Year
1969
Tongue
English
Weight
544 KB
Volume
91
Category
Article
ISSN
0002-7863

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Enantioselectively catalyzed hydrolysis
โœ Shuji Ono; Hideto Shosenji; Kimiho Yamada ๐Ÿ“‚ Article ๐Ÿ“… 1981 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 218 KB

Catalyzed hydrolysis of p-nitrophenyl esters of N-protected L or D-phenylalanine by optically active hydroxamic acid or dipeptides in the presence of CTABr micelles showed high enantioselectivity (D/L=5.68 for L-ZLysZ(MHX)), demonstrating control of the direction of the enantioselectivity based on t