Stereoselective H2O eliminations in 3- and 4-arcylcyclohexanols under electron impact
✍ Scribed by Joseph Sharvit; Asher Mandelbaum
- Publisher
- John Wiley and Sons
- Year
- 1976
- Tongue
- English
- Weight
- 562 KB
- Volume
- 11
- Category
- Article
- ISSN
- 1076-5174
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## Abstract Competing __ortho__ interactions, involving the CX and the __ortho__‐methyl substituent on the 3‐phenyl moiety, resulting in the eliminations of ^˙^CH~3~ and ^˙^OH/^˙^SH from the molecular ions of 2‐substituted‐3‐(2‐methylphenyl)‐4(3__H__)‐quinazolinones and their thio analogues, were
## Abstract The mass spectra of eight pyrrolo[1,2‐__a__][1,3,5]triazie‐2,4(1__H__, 3__H__)‐diones have been examined. An unusual feature in the fragmentation of those compounds having a 7‐alkoxycarbonyl function, namely loss of the whole ester grouping with concomitant hydrogen rearrangement, is di