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Stereoselective Enzymatic Synthesis of cis-Pellitorine, a Taste Active Alkamide Naturally Occurring in Tarragon

✍ Scribed by Jakob P. Ley; Jens-Michael Hilmer; Berthold Weber; Gerhard Krammer; Ian L. Gatfield; Heinz-Jürgen Bertram


Book ID
102170418
Publisher
John Wiley and Sons
Year
2005
Tongue
English
Weight
35 KB
Volume
2005
Category
Article
ISSN
1434-193X

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Stereoselective Enzymatic Synthesis of c
✍ Jakob P. Ley; Jens-Michael Hilmer; Berthold Weber; Gerhard Krammer; Ian L. Gatfi 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 English ⚖ 120 KB

## Abstract The alkamide __cis__‐pellitorine [(2__E__,4__Z__)‐__N__‐isobutyldeca‐2,4‐dienamide] that occurs naturally in tarragon was prepared in yields up to 80% by lipase‐catalyzed conversion of ethyl 2__E__,4__Z__‐decadienoate, the so‐called pear ester, and isobutylamine both with and without th