𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Stereoselective Enol Tosylation: Preparation of Trisubstituted α,β-Unsaturated Esters

✍ Scribed by Baxter, Jenny M.; Steinhuebel, Dietrich; Palucki, Michael; Davies, Ian W.

Book ID
115544423
Publisher
American Chemical Society
Year
2005
Tongue
English
Weight
161 KB
Volume
7
Category
Article
ISSN
1523-7060

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

A highly stereoselective Michael reactio
A highly stereoselective Michael reaction of simple ester enolates to α,β-unsaturated esters
✍ Masahiko Yamaguchi; Michinori Tsukamoto; Shinya Tanaka; Ichiro Hirao 📂 Article 📅 1984 🏛 Elsevier Science 🌐 French ⚖ 244 KB

Under a proper reaction condition, simple ester enolates add to d,e-unsaturated esters highly stereoselectively to give erythro or threoglutarates. Previously, we have shown that lithium enolates derived from simple monoesters react with fi,p-unsaturated esters to give glutarates in high yiela. 1)

Stereoselective synthesis of α-phenylcha
Stereoselective synthesis of α-phenylchalcogeno-α,β-unsaturated esters
✍ Claudio C. Silveira; Antonio L. Braga; Robson B. Guerra 📂 Article 📅 2002 🏛 Elsevier Science 🌐 French ⚖ 123 KB

Ethyl a-phenylchalcogeno a,b-unsaturated esters were prepared in a stereoselective manner by the reaction of ethyl propiolates with organocuprates, followed by the reaction with the appropriate electrophilic organosulfur, organoselenium or organotellurium source.