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Stereoselective Effects in Reactions of Metal Complexes III. Asymmetric hydrogenation of 5, 7, 7, 12, 14, 14-hexamethyl-1, 4, 8, 11-tetraazacyclotetradeca-4, 11-diene-nickel (II)

✍ Scribed by Maurice Wermeille; Ewa Sledziewska; Klaus Bernauer

Publisher
John Wiley and Sons
Year
1974
Tongue
German
Weight
381 KB
Volume
57
Category
Article
ISSN
0018-019X

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Isomeric cis-2, 9-bis(aminomethyl)-5,7,7,12,14,14-hexameth-in the Ni configuration, which is accompanied by a concomitant change of the macrocycle conformation from a yl-1,4,8,11-tetraazacyclotetradecanes (6a and 6b) and their octahedral (4) and square-planar nickel(II) complexes ( 5) folded to a p