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Stereoselective Coupling Reaction of Dimethylzinc and Alkyne toward Nickelacycles

โœ Scribed by Mori, Takamichi; Nakamura, Toshiyuki; Kimura, Masanari


Book ID
126833167
Publisher
American Chemical Society
Year
2011
Tongue
English
Weight
944 KB
Volume
13
Category
Article
ISSN
1523-7060

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In the presence of indium triflate or gallium chloride, a novel coupling between internal alkynes and aldehydes occurred to give unsaturated ketones and [4+1] annulation products.