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Stereoselective coordination of N-methyl-S-alanine in the diastereomers of sodium oxalatobis(N-methyl-S-alaninato)cobaltate(III)

✍ Scribed by Ernest A. Berends; John G. Brushmiller

Book ID: 103105026
Publisher: Elsevier Science
Year: 1970
Weight: 161 KB
Volume: 6
Category: Article
ISSN: 0020-1650
DOI: 10.1016/0020-1650(70)80175-1

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## Abstract The __cis__‐N/__trans__‐N interconversion of the title compound containing glycine and (__R__)‐ or (__S__)‐leucine has been studied by polarimetric and spectrophotometric techniques. Equilibrium constants were determined on the basis of kinetic and thermodynamic data. It is shown that t