Stereoselective binding of D or L—α-amino acids by Cu(II) complexes of N-benzenesulfonyl-L—α-phenylalanine
✍ Scribed by Daniel Muller; Jacqueline Jozefonvicz; Michel-Alain Petit
- Book ID
- 118330124
- Publisher
- Elsevier Science
- Year
- 1980
- Weight
- 261 KB
- Volume
- 42
- Category
- Article
- ISSN
- 0022-1902
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## Abstract The cupric complexes of poly(__N__^ε^‐acetoacetyl‐L‐lysine), [Lys(Acac)]~n′~ poly(__N__^δ^‐acetoacetyl‐L‐ornithine), [Orn(Acac)]~n′~ and poly(__N__^γ^‐acetoacetyl‐L‐diaminobutyric acid), [A~2~bu‐(Acac)]~n~, as well as of the model compound __n__‐hexyl acetoacetamide, have been investiga
In order to investigate the enzyme model reaction the oxidation of 3,4dihydroxy-L-phenylalanine(L-DOPA) was carried out using optically active catalyst, N-lauroyl L or D-histidine-Cu(I1) complex(L or D-LauHis-Cu(II)), showing appreciable enantioselectivity in the presence of the mixed micelles with